Nuclear Chemical Engineering

[EBN EL NEAL]

Nuclear Chemical Engineering
(McGraw-Hill series in nuclear engineering)
by
Manson Benedict

Publisher

Mcgraw-Hill College

• Number Of Pages: 1024
• Publication Date: 1981-04-01
• Binding: Hardcover

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Nuclear Chemical Engineering
Second Edition
(McGraw-Hill series in nuclear engineering)
by
Manson Benedict, Thomas H. Pigford, Hans Wolfgang Levi

Publisher
Mcgraw-Hill College
Number Of Pages: 1024
Publication Date: 1981-04-01
ISBN-10 / ASIN: 0070045313
ISBN-13 / EAN: 9780070045316
Binding: Hardcover

Content

Chapter 1 Chemical Engineering Aspects of Nuclear Power
Introduction
Nuclear Fission
Nuclear Fuels
Nuclear Reactor Types
Fuel Processing Flow Sheets
Fuel-Cycle Operations
Fuel Reprocessing
lsotope Separation
Nuclear Fusion
References
Problems
Chapter 2 Nuclear Reactions
Nuclides
Radioactivity
Decaychains
Neutron Reactions
The Fission Process
Growth and Decay of Nuclides with Simultaneous Radioactive
Decay, Neutron Absorption, and Continuous Processing
Derivation of the Bateman Equation (2.17) by
Laplace Transforms
Nomenclature
References
Problems
Chapter 3 Fuel Cycles for Nuclear Reactors
Nuclear Fuels
Effects of Irradiation on Nuclear Fuels
Fuel and Poison Management
Fuel Management in a Large Pressurized-Water Reactor
Fuel-Cycle Costs
Hand Calculation of Fuel-Cycle Performance
Fuel-Cycle hiaterial Flow Sheets
Nomenclature
References
Problems
Chapter 4 Solvent Extraction of Metals
Applications
Extractable Metal-Organic Complexes
Solvent Extraction Principles
Distribution Coefficients
Solvent Requirements
Theory of Countercurrent Equilibrium Extraction
Solvent Extraction Equipment
Nomenclature
References
Problems
Chapter 5 Uranium
Uranium Isotopes
Uranium Radioactive Decay Series
Metallic Uranium
Uranium Compounds
Uranium Solution Chemistry
Sources of Uranium
Uranium Resource Estimates
Concentration of Uranium
Uranium Refining
Production of Uranium Metal
References
Problems
Chapter 6 Thorium
Uses of Thorium
Thorium isotopes
Thorium Radioactivity
Metallic Thorium
Thorium Compounds
Thorium Solution Chemistry
Thorium Resources
Concentration and Extraction of Thorium
Purification of Thorium
Conversion of Thorium Nitrate to Oxide, Fluoride,
Chloride, or Metal
References
Problems
Chapter 7 Zirconium and Hafnium
Uses of Zirconium and Hafnium
Natural Occurrence
Production and Rice
Zirconium and Hafnium Metal and Alloys
Zirconium and Hafnium Compounds
Extraction of Zirconium and Hafnium from Zircon
Separation of Zirconium and Hafnium
Production of Metallic Zirconium and Hafnium
Alternatives for Producing Hafnium-Free Zirconium
from Zircon
References
Problems
Chapter 8 Properties of Irradiated Fuel and Other Reactor Materials
Fission-Product Radioactivity
Radioactivity of the Actinides
Effect of Fuel-Cycle Alternatives on Properties
of Irradiated Fuel
Radioactivity from Neutron Activation
Neutron Activity in Recycled Fuel
Nomenclature
References
Problems
Chapter 9 Plutonium and Other Actinide Elements
General Chemical Properties of the Actinides
Properties of Protactinium
Properties of Neptunium
Properties of Plutonium
Properties of Americium
Properties of Curium
References
Problems
Chapter 10 Fuel Reprocessing
Objectives of Reprocessing
Composition of Irradiated Fuel
History of Reprocessing
The Purex Process
Reprocessing Thorium-Based Fuels
Reprocessing LMFBR Fuels
Neptunium Recovery in Reprocessing
Prevention of Criticality in Reprocessing Plants
References
Problems
Chapter 11 Radioactive Waste Management
Introduction
High-Level Waste
Non-High-Level Waste
Special Radioactive Waste
Disposal of Radioactive Waste
Assessment of Long-Term Safety
References
Problems
Chapter 12 Stable Isotopes: Uses, Separation Methods, and Separation Principles
Uses of Stable Isotopes
Isotope Separation Methods
Terminology
Stage Properties
Types of Cascade
The Simple Cascade
The Recycle Cascade
The Ideal Cascade
Close-Separation Cascade
Separative Capacity, Separative Work, and Separation
Potential
Differential Equation for Separation Potential
Equilibrium Time for Isotope Separation Plants
Squared-off Cascade
Generalized Ideal Cascade
Three-Component Isotope Separation
Nomenclature
References
Problems
Chapter 13 Separation of Isotopes of Hydrogen and Other Light Elements
Sources of Deuterium
Deuterium Production Processes and Plants
Separation Factors in Distillation
Distillation of Hydrogen
Distillation of Water
Electrolysis
Electrolysis and Steam-Hydrogen Exchange
Separation Factors in Deuterium Exchange Processes
Number of Theoretical Stages in Exchange Columns
Monothermal Exchange Processes
Dual-Temperature Water-Hydrogen Sulfide Exchange
Process
Dual-Temperature Ammonia-Hydrogen Exchange Process
Methylamine-Hydrogen Exchange Processes
Dual-Temperature Water-Hydrogen Exchange Processes
Exchange Processes for Separation of Lithium Isotopes
Exchange Processes for Other Elements
Nomenclature
References
Problems
Chapter 14 Uranium Isotope Separation
Introduction
Isotopic Content of Uranium
Uranium Enrichment Projects
Gaseous Diffusion
The Gas Centrifuge
Aerodynamic Processes
Mass Diffusion
Thermal Diffusion
Laser Isotope Separation
Nomenclature
References
Problems
Appendixes
A Fundamental Physical Constants
B Conversion Factors
C Properties of the Nuclides
D Radioactivity Concentration Limits for Selected
Radionuclide

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